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Tongji University: A major breakthrough in single diamond!

2024-04-30 16:36:34

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Recently, Professor Han Lu's team from the School of Chemical Science and Engineering of Tongji University made a major breakthrough in the field of photonic crystals and successfully realized the self-assembly construction of a single diamond (SD) curved titanium dioxide skeleton. This achievement is known as the "Holy Grail" of photonic crystal structures. . Relevant research papers have been published in the internationally authoritative academic journal "Proceedings of the National Academy o


Recently, Professor Han Lu's team from the School of Chemical Science and Engineering of Tongji University made a major breakthrough in the field of photonic crystals and successfully realized the self-assembly construction of a single diamond (SD) curved titanium dioxide skeleton. This achievement is known as the "Holy Grail" of photonic crystal structures. . Relevant research papers have been published in the internationally authoritative academic journal "Proceedings of the National Academy of Sciences" (PNAS).


The single diamond (SD) surface structure is commonly found in the exoskeletons of beetles and weevils. The perfect combination of its unique negative Gaussian curvature surface and the cubic diamond lattice network gives these insects brilliant structural colors. The SD structure has the characteristics reported so far. The widest complete photonic band gap, and the complete photonic band gap can be easily achieved using known materials at a dielectric constant contrast of about 1.9. Its excellent optical properties make it suitable for applications such as photonic crystals, light harvesting applications, and optical waveguides. It has broad application prospects in fields such as laser resonators and laser resonators. However, as a thermodynamically metastable structure, the artificial preparation of SD has always been a problem faced by the scientific community.



Professor Han Lu's team successfully achieved efficient preparation of SD structures by introducing the dual synergistic regulation of kinetics and thermodynamics. They used the collaborative self-assembly process of polyethylene oxide-b-polystyrene (PEO-b-PS) copolymer and TiO2 precursor in a specific solvent to precisely control the conditions to achieve the nucleation site of TiO2 oligomers. The spots are enriched and grown, eventually forming an independent SD domain. After removing the polymer template by calcination, a TiO2 framework with a highly ordered SD mesostructure and anatase crystal form was obtained.



Schematic diagram of SD skeleton synthesis strategy


The research team conducted a detailed characterization of the SD skeleton structure through a series of experimental methods. The results of small-angle X-ray scattering and wide-angle X-ray diffraction showed the high degree of order of the sample; observations with scanning electron microscopy and transmission electron microscopy further confirmed the existence and high degree of order of the SD structure; the electrostatic potential density distribution obtained by three-dimensional reconstruction of electron crystallography This proves the four-connection configuration of the SD structure. In addition, calculation results show that the structure has a complete photonic band gap, providing a theoretical basis for its application in photonic crystals and other fields.




Structural characterization of SD skeleton structure before and after roasting




Transmission electron microscopy analysis and three-dimensional structure analysis of SD skeleton




Photonic band gap diagram of SD skeleton structure



Professor Han Lu said that this research result not only solved the problem of synthesizing non-equilibrium structures that has long been pursued in the field of self-assembly, but also provided new ideas and methods for the preparation of other thermodynamic non-equilibrium structures. This method has broad application prospects and important significance in the fields of self-assembly, bionic materials, and next-generation optical devices.Professor Han Lu said that this research result not only solved the problem of synthesizing non-equilibrium structures that has long been pursued in the field of self-assembly, but also provided new ideas and methods for the preparation of other thermodynamic non-equilibrium structures. This method has broad application prospects and important significance in the fields of self-assembly, bionic materials, and next-generation optical devices.




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Tongji University: A major breakthrough in single diamond!
Recently, Professor Han Lu's team from the School of Chemical Science and Engineering of Tongji University made a major breakthrough in the field of photonic crystals and successfully realized the self-assembly construction of a single diamond (SD) curved titanium dioxide skeleton. This achievement is known as the "Holy Grail" of photonic crystal structures. . Relevant research papers have been published in the internationally authoritative academic journal "Proceedings of the National Academy o
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